Cooperativity Between Low-Valent Iron and Potassium Promoters in Dinitrogen Fixation
نویسندگان
چکیده
منابع مشابه
Dinitrogen Fixation in Illinois Bundleflower
Although Illinois bundleflower is known to contribute N in forage systems (Dovel et al., 1990; Posler et al., Symbiotic N2 fixation capacity may affect productivity of the peren1993; Springer et al., 2001), there is a paucity of informanial legume Illinois bundleflower [Desmanthus illinoensis (Michx.) tion on its N2 fixation capability. Nodulation has been MacMill. ex B.L. Rob. & Fernald]. Our ...
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Materials that catalyze efficient electrochemical N2 fixation would open up the possibility of using an N2/NH3 cycle to store and utilize energy from diffuse renewable sources. In such a cycle, N2 and H2O would be electrolytically transformed to NH3 and O2 in an electrolyzer powered by a renewable electricity source. With existing technologies, NH3 can be utilized in solid oxide fuel cells or c...
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Partial male-sterile (ms(4)/ms(4)) soybeans (Glycine max L. Merr.) and their fertile isoline (Ms(4)/Ms(4)) were grown in adjoining field plots. From 62 until 92 days after emergence, the nitrogenase activity, assayed by acetylene reduction, of the average male-sterile plant was approximately twice that of the average fertile plant. At approximately 100 days after emergence, the assayable nitrog...
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Understanding the coordination of dinitrogen to iron is important for understanding biological nitrogen fixation aswell as for designing synthetic systems that are capable of reducing N2 to NH3 undermild conditions. This review discusses recent advances in iron–dinitrogen coordination complexes and describes the factors that contribute to the degree of activation of the coordinatedN2. The react...
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ژورنال
عنوان ژورنال: Inorganic Chemistry
سال: 2012
ISSN: 0020-1669,1520-510X
DOI: 10.1021/ic300150u